Beilstein J. Org. Chem.2019,15, 1226–1235, doi:10.3762/bjoc.15.120
Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, UK 10.3762/bjoc.15.120 Abstract We here explore how ball-mill-grindingfrequency affects the kinetics of a disulfide exchange reaction. Our kinetic data show that the reaction progress is similar at all the frequencies studied (15–30 Hz
grinding; grindingfrequency; kinetics; mechanism; mechanochemistry; Introduction
We describe here an unusual frequency-dependence in the induction period of a covalent reaction carried out using ball-mill grinding. We present a kinetic analysis indicating that this is due to the successive fracture of
factors, including ball-mill jar size, shape and material, ball-bearing size, weight and material, milling frequency, temperature, and the nature and concentration of the added liquid [17][18]. In this paper we investigate how the ball-mill grindingfrequency affects the kinetics of the covalent reaction
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Graphical Abstract
Scheme 1:
Solid-state exchange reaction through ball-mill grinding under neat ball-mill-grinding conditions (...